June 9, 2023 Journal article Open Access

Amayuelas, Eder; Tortora, Marco; Bartolomè, Luis; Littlefair, Josh D.; Paulo, Gonçalo; Le Donne, Andrea; Trump, Benjamin; Yakovenko, Andrey A.; Chorązėwski, Mirosław; Giacomello, Alberto; Zajdel, Paweł; Meloni, Simone; Grosu, Yaroslav

MARC21 XML Export

<?xml version='1.0' encoding='UTF-8'?>
<record xmlns="http://www.loc.gov/MARC21/slim">
  <leader>00000nam##2200000uu#4500</leader>
  <datafield tag="650" ind1="1" ind2="7">
    <subfield code="a">cc-by</subfield>
    <subfield code="2">opendefinition.org</subfield>
  </datafield>
  <datafield tag="520" ind1=" " ind2=" ">
    <subfield code="a">&lt;p&gt;Zeolitic Imidazolate Frameworks (ZIF) find&amp;nbsp;application in storage and dissipation of mechanical energy.&lt;br&gt;
Their distinctive properties linked to their (sub)nanometer size&amp;nbsp;and hydrophobicity allow for water intrusion only under high&amp;nbsp;hydrostatic pressure. Here we focus on the popular ZIF-8 material&amp;nbsp;investigating the intrusion mechanism in its nanoscale cages, which&amp;nbsp;is the key to its rational exploitation in target applications. In this&amp;nbsp;work, we used a joint experimental/theoretical approach&amp;nbsp;combining in operando synchrotron experiments during high-&amp;nbsp;pressure intrusion experiments, molecular dynamics simulations,&amp;nbsp;and stochastic models to reveal that water intrusion into ZIF-8 occurs by a cascade filling of connected cages rather than a&amp;nbsp;condensation process as previously assumed. The reported results allowed us to establish structure/function relations in this&amp;nbsp;prototypical microporous material, representing an important step to devise design rules to synthesize porous media.&lt;/p&gt;</subfield>
  </datafield>
  <datafield tag="980" ind1=" " ind2=" ">
    <subfield code="a">publication</subfield>
    <subfield code="b">article</subfield>
  </datafield>
  <datafield tag="260" ind1=" " ind2=" ">
    <subfield code="c">2023-06-09</subfield>
  </datafield>
  <controlfield tag="005">20230627102330.0</controlfield>
  <controlfield tag="001">77075</controlfield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="a">Tortora, Marco</subfield>
  </datafield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="a">Bartolomè, Luis</subfield>
  </datafield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="a">Littlefair, Josh D.</subfield>
  </datafield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="a">Paulo, Gonçalo</subfield>
  </datafield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="a">Le Donne, Andrea</subfield>
  </datafield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="a">Trump, Benjamin</subfield>
  </datafield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="a">Yakovenko, Andrey A.</subfield>
  </datafield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="a">Chorązėwski, Mirosław</subfield>
  </datafield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="a">Giacomello, Alberto</subfield>
  </datafield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="a">Zajdel, Paweł</subfield>
  </datafield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="a">Meloni, Simone</subfield>
  </datafield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="a">Grosu, Yaroslav</subfield>
  </datafield>
  <datafield tag="542" ind1=" " ind2=" ">
    <subfield code="l">open</subfield>
  </datafield>
  <datafield tag="100" ind1=" " ind2=" ">
    <subfield code="a">Amayuelas, Eder</subfield>
  </datafield>
  <datafield tag="245" ind1=" " ind2=" ">
    <subfield code="a">Mechanism of Water Intrusion into Flexible ZIF-8: Liquid Is Not Vapor</subfield>
  </datafield>
  <datafield tag="856" ind1="4" ind2=" ">
    <subfield code="s">5215042</subfield>
    <subfield code="u">https://www.openaccessrepository.it/record/77075/files/acs.nanolett.3c00235.pdf</subfield>
    <subfield code="z">md5:714de66ce52fd3d32ef8af6bec602585</subfield>
  </datafield>
  <datafield tag="540" ind1=" " ind2=" ">
    <subfield code="u">https://creativecommons.org/licenses/by/4.0/</subfield>
    <subfield code="a">Creative Commons Attribution 4.0</subfield>
  </datafield>
  <datafield tag="024" ind1=" " ind2=" ">
    <subfield code="a">10.1021/acs.nanolett.3c00235</subfield>
    <subfield code="2">doi</subfield>
  </datafield>
</record>